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生物质纤维素/氢氧化镁复合材料的实验和第一性原理计算探索:局部结构、界面相互作用和抗菌性能
International Journal of Biological Macromolecules
(
IF
7.7
)
Pub Date : 2021-09-25
, DOI:
10.1016/j.ijbiomac.2021.09.135
Xin-Yu Wang
1
,
Jing-Heng Nie
2
,
Nian-Dan Zhao
3
,
Yu-Chang Hou
3
,
Yuan-Ru Guo
2
,
Shujun Li
2
,
Qing-Jiang Pan
3
Affiliation
- Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China; Key Laboratory of Functional Inorganic Material Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China.
- Key Laboratory of Bio-based Material Science & Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China.
- Key Laboratory of Functional Inorganic Material Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China.
生物质复合材料局部结构的规范和界面相互作用的澄清对于合成新材料和提高其在各种苛刻应用中的性能具有重要意义。然而,由于实验技术的限制,它仍然具有挑战性,特别是生物质复合材料通常在活性位点和界面附近具有氢键的方式。在此,纤维素/Mg(OH) 2纳米复合材料已通过简单的水热方法合成,并通过密度泛函理论 (DFT) 计算进行检验。复合材料呈现层状形态;Mg(OH) 2薄片大小约为 50 nm 且分散良好。它们要么锚定在纤维素表面上,要么嵌入层间。特定的复合结构在理论上得到了证实,与 XRD、SEM 和 TEM 观察结果一致。发现界面相互作用是氢键。对于包含三个纤维素链和两层 Mg(OH) 2簇的复合模型,计算出每个羟基的平均吸附能在 -0.47 和 -0.26 eV 之内。组合计算/实验结果允许假设纳米复合材料的抗菌机制。
"点击查看英文标题和摘要"
Experimental and first-principle computational exploration on biomass cellulose/magnesium hydroxide composite: Local structure, interfacial interaction and antibacterial property
The specification of the local structure and clarification of interfacial interactions of biomass composites is of tremendous significance in synthesizing novel materials and advancing their performance in various demanding applications. However, it remains challenging due to the limitations of experimental techniques, particularly for the manner that biomass composites commonly have hydrogen bonds involved in the vicinity of active sites and interfaces. Herein, the cellulose/Mg(OH)2 nanocomposite has been synthesized via a simple hydrothermal approach and examined by density functional theory (DFT) calculations. The composite exhibits a layered morphology; Mg(OH)2 flakes are around 50 nm in size and well-dispersed. They either anchor onto the cellulose surface or intercalate between layers. The specific composite structure was confirmed theoretically, in line with XRD, SEM and TEM observations. The interfacial interactions were found to be hydrogen bonding. The average adsorption energy per hydroxyl group was computed to be within −0.47 and −0.26 eV for a composite model comprising three cellulose chains and a two-layered Mg(OH)2 cluster. The combined computational/experimental results allow to postulate the antibacterial mechanism of the nanocomposite.
更新日期:2021-09-28